Highlights The robust organic/inorganic hybrid interlayer derived from in situ formed tribofilms were fabricated by using a scalable rolling method. The interlayer facilitates dendrite-free lithium metal anodes by building local de-solvation environments near the interface and inhibiting both dendrite growth and electrolytes corrosion. The symmetrical cell exhibits a remarkable lifesp... https://www.tftoyes.shop/product-category/armada/